Cobalt(ii) liquid metal salts for high current density electrodeposition of cobalt
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منابع مشابه
High current density electrodeposition of silver from silver-containing liquid metal salts with pyridine-N-oxide ligands.
New cationic silver-containing ionic liquids were synthesized and used as non-aqueous electrolytes for the electrodeposition of silver layers. In the liquid state of these ionic liquids, a silver (i) cation is coordinated by pyridine-N-oxide (py-O) ligands in a 1 : 3 metal-to-ligand ratio, although in some cases a different stoichiometry of the silver center crystallized out. As anions, bis(tri...
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Liquid metal salts are electrolytes with the highest possible metal concentration for electrodeposition, because the metal ion is an integral part of the solvent. This paper introduces the new ionic silver complexes [Ag(MeCN)(4)](2)[Ag(Tf(2)N)(3)], [Ag(MeCN)][Tf(2)N] and [Ag(EtIm)(2)][Tf(2)N], where MeCN stands for acetonitrile, EtIm for 1-ethylimidazole and Tf(2)N is bis(trifluoromethylsulfony...
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Several organs (lung, skin, thyroid, heart, bone marrow) are potential targets of cobalt (Co). Whereas there is no doubt that inhalation of Co alone may cause bronchial asthma, its role in the occurrence of hard metal disease is still controversial because most cases were reported in workers exposed not only to Co but also to other substances such as tungsten carbide, titanium carbide, iron, si...
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New homoleptic and heteroleptic zinc(ii)-containing liquid metal salts with N-alkylimidazole (AlkIm) ligands and bis(trifluoromethylsulfonyl)imide (Tf2N(-)) anions are described. The general formulae of the complexes are [Zn(AlkIm)6][Tf2N]2 and [Zn(AlkIm)6-x(AlkIm')x][Tf2N]2. Single-crystal X-ray diffraction revealed that, in the solid state, the cations consist of octahedral zinc(ii) centres. ...
متن کاملCathodic Electrodeposition and Characterization of YAG Nanostructure: Effect Current Density on the Morphology
Abstract YAG (Yttrium Aluminum Garnet) was successfully prepared through cathodic electrodeposition process using applying different current densities to the mixture of YCl3 and AlCl3 dissolved in water/ethanol 1:1 solution. Hydroxide precursors were cathodically grown on the cathode surface (at different current densities) and then the obtained hydroxide powder was heat-treated at 1100 °...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2018
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c8dt00283e